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High-energy nickel (Ni)–rich cathode will play a key role in advanced lithium (Li)–ion batteries, but it suffers from moisture sensitivity, side reactions, and gas generation. We observe reversible planar gliding and microcracking along the (003) plane in a single-crystalline Ni-rich cathode. —Bi et al.
Out of several candidates that could replace Li in rechargeable batteries, calcium (Ca) stands out as a promising metal. Not only is Ca 10,000 times more abundant than Li, but it can also yield—in theory—similar battery performance.
British battery R&D company Faradion has demonstrated a proof-of-concept electric bike powered by sodium-ion batteries at the headquarters of Williams Advanced Engineering, which collaborated in the development of the bike. Sodium-ion intercalation batteries—i.e., Oxford University was also a partner. Earlier post.)
Cycling performance of Li/SeS 2 ?C, Researchers at Argonne National Laboratory have developed selenium and selenium–sulfur (Se x S y )-based cathode materials for a new class of room-temperature lithium and sodium batteries. Unlike the widely studied Li/S system, both Se and Se x S y can be cycled to high voltages (up to 4.6
The Li-containing entropy-stabilized oxyfluoride (Li x (Co 0.2 V vs. Li + /Li, enabling its use as a cathode active material. The introduction of monovalent fluorine into the anion lattice of HEO, occupied by divalent oxygen, is charge compensated by incorporation of monovalent lithium (or sodium) into the cation lattice.
Researchers from Nanyang Technical University (NTU) in Singapore have shown high-capacity, high-rate, and durable lithium- and sodium-ion battery (LIB and NIB) performance using single-crystalline long-range-ordered bilayered VO 2 nanoarray electrodes. The VO 2 nanoarrays are supported on graphene foam (GF) and coated with a thin (?2
This includes research on appropriate anodes, cathodes, and electrolytes for magnesium (Mg)-, sodium (Na)-, and lithium (Li)-based batteries and novel transition metal oxide- and nitride-based supercapacitor electrode materials. Magnesium is much more abundant in the Earth’s crust, making it less expensive than Li by a factor of 24.
Recently, the technique has been miniaturized into a handheld device (HH LIBS) capable of analyzer any element, depending on the spectrometer range chosen for the device. LIBS has been used for more than 30 years as a laboratory technique, capable of analyzing any element in the periodic table. Don’t need REE performance?
A direct borohydride fuel cell—first demonstrated in the early 1960s—is a type of alkaline fuel cell directly fed by a sodium borohydride or potassium borohydride solution. The peak power densities ranged at 20–200 mW·cm -2 when Pt or Pt-based catalysts are used, while they were in ca. —Yang et al.
They include the desire to increase the driving range of more modestly priced electric cars from 150 to well over 500 km, and the need to lower the cost and provide maintenance-free technologies for grid applications. Note the trend in abundances of Al > Ca > Mg > Na > Li, and Fe > Mn > Ni > Co. —Grey and Tarascon.
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