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New smelting reduction process to recover Co, Ni, Mn, and Li simultaneously from Li-ion batteries

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A team from metals research institute SWERIM in Sweden reports on a smelting reduction process to recover cobalt, nickel, manganese and lithium simultaneously from spent Li-ion batteries. The absence of a slag allows a nearly 100% recovery of Co, Ni, and Mn in the formed alloy and a nearly 100% recovery of lithium in the flue dust.

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Fluorine-incorporated interface enhances cycling stability of Li metal batteries with Ni-rich NCM cathodes

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Li metal anodes and Ni-rich layered oxide cathodes with high reversible capacities are promising candidates for the fabrication of high energy density batteries. Li/Li + ). O 2 full cell, with a high Coulombic efficiency of 99.98% after 100 cycles at 25 °C. —Lee et al. Yongwon Lee et al. 2019.104309.

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Researchers in Korea propose graphene/Ni foam as Li metal storage medium for advanced batteries

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Researchers in Korea have developed three-dimensional monolithic corrugated graphene on nickel foam electrode as a Li metal storage framework in carbonate electrolytes. Therefore, hybrid engineering to prevent dendritic Li growth and increase the coulombic efficiency in highly reactive electrolytes is essential. —Kang et al.

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MIT electrolyte enables ultra-high voltage Ni-rich cathodes in Li-metal batteries

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The electrolyte not only suppresses side reactions, stress-corrosion cracking, transition-metal dissolution and impedance growth on the cathode side, but also enables highly reversible Li metal stripping and plating on the lithium-metal anode (LMA), leading to a compact morphology and low pulverization. Huang, M.,

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UMD team uses high concentration of LiFSI salt to suppress dendrite formation on Li-metal anode; paired with Ni-rich cathode

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of Li deposition and stripping, along with an anodic stability of >5.5 Pairing a Li-metal anode in this electrolyte with and LiNi 0.6 mAh/cm 2 ) created a NMC622||Li cell, which showed a high capacity retention of 86% after 100 cycles at a high cutoff voltage of 4.6 Pairing a Li-metal anode in this electrolyte with and LiNi 0.6

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Nanjing researchers design new Li-rich layered cathode

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Researchers at Nanjing University (China) have introduced a new layered C2/m oxide—Li 2 Ni 0.2 Compared with Li 2 MnO 3 (LMO), LNMR displays superior capacity, a more stable capacity retention rate, higher energy density and average discharge voltage. In such materials, 1/3 of the TM sites are occupied by Li phase.

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Navy researchers boost performance of Ni-Zn cells commensurate with Li-ion; safer alternative

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Despite these disadvantages, Li-ion batteries are widely used because they provide high energy density, high specific power, and long cycle life—attributes that must also be met by any alternative battery system in order to compete for market share. The shaded areas highlight the specific energy range of common battery chemistries.

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