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Long-term discharge curve of the newly developed lithium-air cell. Researchers at Japan’s AIST (National Institute of Advanced Industrial Science and Technology) are developing a lithium-air cell with a new structure (a set of three different electrolytes) to avoid degradation and performance problems of conventional lithium-air cells.
Argonne National Laboratory, which has contributed heavily to the research and development of Li-ion battery technology, is now pursuing research into Lithium-air batteries. Li-air batteries use a catalytic air cathode that converts oxygen to lithium peroxide; an electrolyte; and a lithium anode.
General schematic of a lithium-air battery. The team plans to explore rechargeable Lithium-Air systems, which could offer 10 times the energy capacity of lithium-ion systems. Original lithium-air batteries—aqueous batteries, or with an aqueous electrolyte/air interface—were primary cells—i.e.,
Schematic representation and operating principles of the lithium–water electrochemical cell used for hydrogen generation: (1) external circuit and (2) inside of lithium–water electrochemical cell. the high-school chemistry demonstration of the violent reaction between sodium and water.). Source: Wang et al.
The elimination of the lithium metal anode addresses one of the major issues affecting the development of the lithium-air battery: the safety hazard of the anode. “ The electrolyte used was a solution of a lithium triflate salt (LiCF 3 SO 3 ) in tetraethylene glycol dimethyl ether (TEGDME) adsorbed in a glass fiber separator.
PolyPlus Battery Company is headquartered in Berkeley, CA, and invented and patented the protected lithium electrode (PLE)—a core technology for lithium-sulfur, lithium-air, and lithiumwater batteries.
Although several attempts have been made on the anode materials, the main disadvantages is that their energy density is still much lower than that of conventional lithium ion batteries due to the narrow electrochemical window of water. Here we introduce a coating layer on lithium metal. —Wang et al. —Wang et al.
Lithium-air batteries, with a theoretical gravimetric energy density of ?3500 air” battery technology usable at ambient conditions, it is critical to elucidate the effects of the other constituents of air (N 2 , Ar, H 2 O, and CO 2 ) on the operations of the Li?air air battery. —Lim et al. Batteries'
MIT researchers have found a new family of highly active catalyst materials that provides the best performance yet in the oxygen evolution reaction (OER) in electrochemical water-splitting—a key requirement for energy storage and delivery systems such as advanced fuel cells and lithium-air batteries. Earlier post.)
The researchers produced an array of nanowires, each about 80 nanometers across, using the genetically modified M13 virus, which Dr. Belcher and others have shown can capture molecules of metals from water and bind them into structural shapes. In this case, the manganese oxide nanowires were actually made by the viruses. —Oh et al.
Water will be the primary byproduct. A novel metal complex for electrolysis of water will be used to generate the hydrogen at high rates. Li-Air Battery : Development Of Ultra-high Specific Energy Rechargeable Lithium/Air Batteries Based On Protected Lithium Metal Electrodes. per gallon. Harvard, Univ.
Advanced systems such as lithium-air, sodium-ion, as well as lithium-ion with new cathode chemistries are appropriate. Advanced Batteries for Transportation. The focus is on high-energy density and high-power density batteries suitable for transportation applications.
Advanced systems such as lithium-air, sodium-ion, as well as lithium-ion electrochemical energy storage are appropriate. Photocatalytic or photoelectrochemical processes for the splitting of water into H 2 gas, or for the reduction of CO 2 to liquid or gaseous fuels are appropriate.
The top two awards, one of $9 million to a project led by Dow Chemical, and one of $8.999 million to a project led by PolyPlus, will fund projects tackling, respectively, the manufacturing of low-cost carbon fibers and the manufacturing of electrodes for ultra-high-energy-density lithium-sulfur, lithium-seawater and lithium-air batteries.
Lithium-air (or lithium-oxygen) batteries potentially could offer three times the gravimetric energy of current Li-ion batteries (3500 Wh/kg at the cell level); as such, they are looked to a potential solution for long-range EVs. V), where Li 2 O 2 is formed largely by disproportionation of LiO 2 , and at low potentials (~2.2
Just a few examples of transportation-related neutron-assisted research at ORNL include: Using neutron-computed tomography, researchers at the CG-1D neutron imaging instrument at HFIR successfully mapped the 3D spatial distribution of lithium products in electrochemically discharged lithium-air cathodes. Images of GDI injector.
Advanced systems such as lithium-air, sodium-ion, as well as lithium-ion electrochemical energy storage are appropriate. Advanced Batteries for Transportation and Renewable Energy Storage. The focus is on high-energy density and high-power density batteries suitable for transportation and renewable energy storage applications.
Conventional lithium-air batteries draw in oxygen from the outside air to drive a chemical reaction with the battery’s lithium during the discharging cycle, and this oxygen is then released again to the atmosphere during the reverse reaction in the charging cycle. —Zhu et al.
Also on the list of five is the arrival of advanced batteries, including air batteries (e.g., Lithiumair), but targeted initially at small devices. By having water flow so close to each chip, heat can be removed more efficiently. Earlier post.).
While the results, reported in the journal Science , are promising, the researchers caution that a practical lithium-air battery still remains at least a decade away. This battery cycles via LiOH formation, not Li 2 O 2 , and is able to tolerate large quantities of water. volt, and impressive rechargeability. —Liu et al.
In addition to a detailed discussion of the possible dynamics of the electrochemistry of the cell, the authors note that there are other issues that need to be addressed, including the lithium anode, as well as the question of Li-air or Li-O 2 batteries—e.g., Wilcke (2010) Lithium-Air Battery: Promise and Challenges.
Theoretically, with renewable electricity, the 95 gCO 2 /km target could also be met by extended range electric vehicles with 40 miles all-electric range if 50% of driving is powered by the battery, or by fuel cell electric vehicles (FECVs), with hydrogen produced by water electrolysis. While the so-called post-LiBs, viz.,
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