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PNNL: single-crystal nickel-rich cathode holds promise for next-generation Li-ion batteries

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High-energy nickel (Ni)–rich cathode will play a key role in advanced lithium (Li)–ion batteries, but it suffers from moisture sensitivity, side reactions, and gas generation. The gliding occurs as the battery charges and discharges—lithium ions depart and return to cathode, straining the crystal ever so slightly each time.

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PNNL team develops electrolyte for high-voltage sodium-ion battery with extended longevity

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Cheap and abundant, sodium is a promising candidate for new battery technology. However, the limited performance of sodium-ion batteries has hindered large-scale application. Sodium-ion batteries (NIBs) have attracted worldwide attention for next-generation energy storage systems. —Jin et al. 2 in mole or 1.6:8.4

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WSU, PNNL researchers develop viable sodium battery

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Although O3-layered metal oxides are promising cathode materials for high-energy Na-ion batteries, they suffer from fast capacity fade. However, the nickel rich O3-NaTMOs suffer from irreversible phase transition at high voltage and limited cycle life, similar to their Li analogues, if not even worse.

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Study identifies halogen-free superhalogen electrolytes for Li-ion batteries

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Most electrolytes currently used in Li-ion batteries contain halogens, which are toxic. An in-depth study based on first-principles calculations by researchers at Virginia Commonwealth University has shown that the anions of commercially available electrolytes for Li-ion batteries are all superhalogens. —Giri et al.

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New high energy, highly stable cathode for sodium-ion batteries

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F 0.7 , for sodium-ion (Na-ion) batteries (NIBs). This new material provides an energy density of 600 Wh kg –1 , the highest value among Na-ion cathodes. Recently, attention has been refocused on room-temperature Na-ion batteries (NIBs) as a low-cost alternative technology as compared to LIBs. Click to enlarge.

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KAUST team devises electrically-driven membrane process for seawater lithium mining

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ppm) with a nominal Li/Mg selectivity >45 million. ppm) and an abundance of interfering ions (i.e., 13000 ppm of sodium, magnesium, calcium, and potassium ions, among others). Instead, the lithium concentration and the ratio of lithium to other multivalent ions, such as Mg 2+ and Ca 2+ , are the key factors to consider.

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Chalmers team develops graphite-like anode for Na-ion batteries; Janus graphene

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Researchers at Chalmers University of Technology, Sweden, have developed a nanometric graphite-like anode for sodium ion (Na + storage), formed by stacked graphene sheets functionalized only on one side, termed Janus graphene. The estimated sodium storage up to C 6.9 100 to 150 mA h g ? 100 to 150 mA h g ?1

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