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A study by a team of researchers from Technische Universität Berlin (TUB) and Fritz-Haber-Institut der Max-Planck-Gesellschaft has found that direct seawater splitting for hydrogen production has substantial drawbacks compared to conventional water splitting and offers almost no advantage. Diess et al.
Stanford researchers, with a colleague from King Fahd University of Petroleum and Minerals, have developed a simple and environmentally sound way to make ammonia with tiny droplets of water and nitrogen from the air. The conversion rate reaches 32.9 ± 1.38 Water microdroplets are the hydrogen source for N 2 in contact with Fe 3 O 4.
Photoelectrochemical (PEC) water splitting based on solar energy is one promising approach for the production of green hydrogen. However, its widespread application is limited by a lack of efficient photoanodes for catalyzing the rate-limiting oxygen evolution reaction (OER), an important reaction in PEC water splitting.
Researchers at the University of Southampton have transformed optical fibers into photocatalytic microreactors that convert water into hydrogen fuel using solar energy. The researchers have published their proof-of-concept in ACS Photonics and will now establish wider studies that demonstrate the scalability of the platform.
Researchers in Israel have designed a separate-cell photoelectrochemical (PEC) water-splitting system with decoupled hydrogen and oxygen cells for centralized hydrogen production. A paper describing their system is publishedin the journal Joule. The hydrogen cell contains the cathode, and it is physically separated from the oxygen cell.
Researchers at the University of Cambridge, with colleagues at the University of Tokyo, have developed a standalone device that converts sunlight, carbon dioxide and water into formic acid, a carbon-neutral fuel, without requiring any additional components or electricity. —senior author Professor Erwin Reisner. Qian Wang et al.
eutrophication; ET = ecological toxicity; FEC = fossil energy consumption; WU = water use; LO = land occupation; “The rest” includes acidification; smog formation; ozone layer depletion; and human health effects. For gasoline, the study reflects the US context in which crude oil is to a large extent imported and refined domestically.
ReactWell , LLC, has licensed a novel waste-to-fuel technology from the Department of Energy’s Oak Ridge National Laboratory to improve energy conversion methods for cleaner, more efficient oil and gas, chemical and bioenergy production. —Brandon Iglesias, inventor of the ReactWell process.
The Dutch Institute for Fundamental Energy Research ( DIFFER ) is partnering with Toyota Motor Europe (TME) to develop a device that absorbs water vapor, and splits it into hydrogen and oxygen directly using solar energy. Over the last year, DIFFER and TME demonstrated in a joint feasibility study that the envisioned principle works.
The optimized photo-electrochemical water splitting device uses light absorbers made of silicon arranged in closely packed pillars, dotted with tiny clusters of the new molybdenum sulfide catalyst. An alternative, clean method is to make hydrogen fuel from sunlight and water via a photo-electrochemical (PEC, or water-splitting) process.
Researchers at UC Santa Barbara have developed an efficient, autonomous solar water-splitting device based on a gold nanorod array in which essentially all charge carriers involved in the oxidation and reduction steps arise from the hot electrons resulting from the excitation of surface plasmons in the nanostructured gold (plasmonic water-splitter).
Researchers from the University of Twente in The Netherlands have developed a new high-entropy perovskite oxide (HEO) as a high-activity electrocatalyst for the oxygen evolution reaction (OER)—the key kinetically limiting half-reaction in several electrochemical energy conversion technologies, including green hydrogen generation.
In working to elucidate the chemistry of hydrodeoxygenation (HDO) for the catalytic upgrading of pyrolytic bio-oil to fuel-grade products, researchers at Pacific Northwest National Laboratory (PNNL) have discovered that water in the conversion process helps form an impurity which, in turn, slows down key chemical reactions.
Researchers from the US Department of Energy’s (DOE) Argonne National Laboratory have combined two membrane-bound protein complexes to perform a complete conversion of water molecules to hydrogen and oxygen. An open-access paper describing their work is published in the journal Chemical Science. —Utschig et al.
Reintroducing airships into the world’s transportation mix could contribute to lowering the transport sector’s carbon emissions and can play a role in establishing a sustainable hydrogen based economy, according to a new IIASA-led study. The open-access paper is published in the journal Energy Conversion and Management: X.
A research group led by Associate Professor Takashi Tachikawa of Kobe University’s Molecular Photoscience Research Center has developed a strategy that greatly increases the amount of hydrogen produced from sunlight and water using hematite (??Fe Mesocrystal photoanode formation and photochemical water splitting characteristics.
The mesh with BiVO 4 nanowire photoanode for water oxidation and Rh-SrTiO 3 nanowire photocathode for water reduction produces hydrogen gas without an electron mediator. When immersed in water with visible light irradiation (? ? In the present study, we developed a new architecture for direct solar water-splitting.
Researchers at the University of Oregon have advanced the effectiveness of the catalytic water dissociation reaction in bipolar membranes. The technology behind bipolar membranes, which are layered ion-exchange polymers sandwiching a water dissociation catalyst layer, emerged in the 1950s. —Oener et al. —Shannon Boettcher.
Designing an artificial leaf that uses solar energy to convert water cheaply and efficiently into hydrogen and oxygen is one of the goals of BISfuel (Bio-inspired Solar fuel production)—the Energy Frontier Research Center, funded by the Department of Energy, in the Department of Chemistry and Biochemistry at Arizona State University.
Cool Planet has devised a biomass-to-liquids thermochemical conversion process that simultaneously produces liquid fuels and sequesterable biochar useful as a soil amendment. The output from each catalytic array when cooled is comprised of volatile gases, renewable fuel and water. Earlier post.). Depending on the temperature (300 ?C
The team also suggested that algae systems can be either net energy positive or negative depending on the specific combination of cultivation and conversion processes used. In this new study, reported in the ACS journal Environmental Science & Technology , Clarens et al. Earlier post.) Arrow widths are proportional to mass flows.
Michael Grätzel at EPFL (Ecole Polytechnique Fédérale de Lausanne) in Switzerland has developed a highly efficient and low-cost water-splitting cell combining an advanced perovskite tandem solar cell and a bi-functional Earth-abundant catalyst. conversion efficiency from solar energy to hydrogen, a record with earth-abundant materials.
One-pot electrolytic process produces H 2 and solid carbon from water and CO 2. In this study, they focused on the electrolysis component for STEP fuel, producing hydrogen and graphitic carbon from water and carbon dioxide. In this study, we focus on the electrolysis component for STEP fuel. Click to enlarge.
This project will complete key engineering design and demonstration tests to enable cost-competitive, carbon-neutral production of synthetic jet fuel and diesel using nuclear energy from existing light water reactors.
Based on visual interpretation of high-resolution (30 m) satellite images, a new study in the journal Global Change Biology: Bioenergy determined that industrial plantations covered over 3.1 That number is in my opinion conservative, and consistent with a slight reduction in the rate of peat conversion. —Miettinen et al.
An open access paper on their study is published in Biotechnology for Biofuels. The complex physical and chemical interactions between these components prevent enzymes from readily accessing the microfibrillar cellulose during the saccharification stage of its conversion into biofuel. —Littlewood et al. Littlewood et al.
Using a hematite photocatalyst, a team led by researchers from Kobe University has succeeded in producing both hydrogen gas and hydrogen peroxide at the same time from sunlight and water. Recently, they have succeeded in increasing the light energy conversion efficiency by applying this technology to hematite (?-Fe under 600nm).
A study by a team from the Great Lakes Bioenergy Research Center (GLBRC) has found that perennial biofuel crops’ evapotranspiration does not differ greatly from corn. Land conversion to biofuel production is an example of a potential large-scale land cover change. —Hamilton et al.
storage and conversion, catalysis, gas adsorption and storage, drug and enzyme delivery, and water treatment. Over the past decade they have begun to play an important role in areas such as energy storage and conversion, catalysis, gas adsorption and storage, drug and enzyme delivery, and water treatment. at 0 °C and 2.9
Conversion of large swaths of Brazilian land for sugar plantations will help the country meet its needs for producing cane-derived ethanol, but it also could lead to regional climate effects, according to a team of researchers from Arizona State University, Stanford University and the Carnegie Institution for Science. millimeters per day.
A two-year study commissioned by Airbus and partners including Virgin Australia in 2012 into the practicability of using Australia’s mallee trees to make biofuels suitable for powering passenger jets ( earlier post ) has reported encouraging results. John McGrath, CRC Research Director.
By using a water-lean post-combustion capture solvent, (N-(2-ethoxyethyl)-3-morpholinopropan-1-amine) (2-EEMPA), they achieved a greater than 90% conversion of captured CO 2 to hydrocarbons—mostly methane—in the presence of a heterogenous Ru catalyst under relatively mild reaction conditions (170 °C and 2 pressure).
The new PNNL carbon capture and conversion system brings the cost to capture CO 2 down to about $39 per metric ton. This is the first known demonstration of integrated low-temperature thermocatalytic capture and conversion of CO 2 to methanol in an economically viable CO 2 capture solvent. gal ($470/metric ton), is presented.
A key benefit of this joint effort is the direct coordination of NSF-funded use-inspired basic research and EERE-funded applied R&D toward the development of cost-effective large-scale systems for the low-carbon production of hydrogen through advanced solar water-splitting technologies.
While Ni metal catalyzes the hydrogen evolution reaction (HER) exclusively under CO 2 RR conditions, Ni single atomic sites present a high CO selectivity of 95% under an overpotential of 550 mV in water, and an excellent stability over 20 hours’ continuous electrolysis. The current density can be scaled up to more than 50 mA cm?2
Researchers at Argonne National Laboratory have analyzed the water consumption for transportation fuels in the United States using an extended lifecycle system boundary that includes the water embedded in intermediate processing steps. Increases in population, energy and food demand now strain previously abundant sources of water.
Schematic representation of the integrated conversion of hemicellulose and cellulose portions of lignocellulosic biomass to furfural and GVL, using a portion of the GVL as a solvent and the remainder for conversion to butene oligomers as hydrocarbon. 80%) from direct conversion of hemicellulose in corn stover. Alonso et al.
The process, reported in the ACS journal Energy & Fuels , could leverage a recently reported process, also developed by NRL, to recover CO 2 from sea water. The mechanism of the first stage first produces CO and water. The water formed in the primary reactions negatively influences catalyst activity and product selectivity.
volts versus the reversible hydrogen electrode) in CO-saturated alkaline water. —Matthew Kanan, an assistant professor of chemistry at Stanford and coauthor of the Nature study. For the Nature study, Kanan and Li built an electrochemical cell: two electrodes placed in water saturated with carbon monoxide gas.
One way to mitigate high feedstock cost is to maximize conversion into the bioproduct of interest. This maximization, though, is limited because of the production of CO 2 during the conversion of sugar into acetyl-CoA in traditional fermentation processes. In this study, researchers tested how C. Wiedel, Jennifer Au, Maciek R.
Qiang Dai and Christian Lastoskie found that BEVs and FCVs in particular offer significant reductions in greenhouse gas emissions, especially if carbon capture and sequestration (CCS) technologies are implemented at the fuel conversion facilities. Their study appears in the ACS journal Energy & Fuels. … water depletion potential (WDP).
A new study, led by academics at St John’s College, University of Cambridge, has used semi-artificial photosynthesis to explore new ways to produce and store solar energy. They used natural sunlight to convert water into hydrogen and oxygen using a mixture of biological components and manmade technologies. Katarzyna P.
Their quantitative lifecycle assessment of the environmental merits of liquid hydrocarbon fuels produced from CO 2 , water and energy compared to alternative fuel production routes is published in the ACS journal Environmental Science & Technology. R indicates reference alternatives not explicitly modeled in this study.
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