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Hydrogen is produced in a catalytic hydrolysis reaction of sodium borohydride (NaBH 4 ) with ruthenium powder as a catalyst. The system consists of two main chambers: an upper chamber with granulated sodium borohydride powder and a lower reaction chamber with a solution of water and catalyst. Zakhvatkin et al. 1c00367.
In April, the company completed the diesel hydrotreater conversion, which will ramp up to 8,000 bbl/d (120 million gallons per year) of renewable diesel production by the third quarter of 2021. Subject to permitting and approvals, full conversion of the refinery is expected in early 2024. Earlier post.).
Pacific Gas and Electric Company (PG&E) and the California Energy Commission today unveiled a utility-scale sodium-sulfur battery energy storage system ( earlier post ) pilot project to better balance power needs of the electric grid. The system has a 4 megawatt capacity, and can store more than six hours of energy.
Scheme of the new full sodium-ion battery, which combines an intercalation cathode and a conversion anode. This battery system combines an intercalation cathode and a conversion anode, resulting in high capacity, high rate capability, thermal stability, and much improved cycle life. (In Credit: ACS, Oh et al. Click to enlarge.
Researchers led by the Department of Energy’s Pacific Northwest National Laboratory (PNNL) have extended the capacity and duration of sodium-aluminum batteries. The new sodium-based molten salt battery uses two distinct reactions. of peak charge capacity. mAh cm −2 , a discharge duration of 28.2
The electrochemical cells created by Kanan and his team combat these inefficiencies with a modified design that produces a concentrated stream of ethylene gas and a sodium acetate solution 1,000 times more concentrated than product obtained with previous cells. —Ripatti et al. —Matthew Kanan. Ripatti et al. 2018.10.007.
RAL researchers are proposing a new process for the decomposition of ammonia to release hydrogen that involves the stoichiometric decomposition and formation of sodium amide from Na metal. To date, very few candidates show potential beyond that of the seminal work on titanium-doped sodium alanate. Credit: ACS, David et al.
Researchers from Ulsan National Institute of Science and Technology (UNIST) in Korea and Karlsruher Institute of Technology in Germany have developed a novel energy conversion and storage system using seawater as a cathode. Similarly, sodium has recently attracted attention as a replacement for lithium in alkali-metal-air batteries.
Tests conducted by Titirici Group , a multidisciplinary research team based at Imperial College London, have found that a novel carbon nanotube electrode material derived from CO 2 —produced by Estonian nanotech company UP Catalyst ( earlier post )—enhances the cyclability of sodium-ion batteries.
nm, average) of iron pyrite (FeS 2 ) nanoparticles are advantageous to sustain reversible conversion reactions in sodium ion and lithium ion batteries. In this work we explore the sodium and lithium conversion of ultrafine FeS 2 nanoparticles, with a tight size distribution centered around ∼4.5
The high thermoelectric figure of merit is expected to enable the conversion of 14% of heat waste to electricity. And a team from Northwestern University and the University of Michigan reported experimentally achieving a ZT of 1.7 at ~800 K (527 °C) by structurally modifying lead telluride. The study by Biswas et al. at ~800 K.
Natron Energy , a developer of new battery cell technology based on Prussian Blue analogue electrodes and a sodium-ion electrolyte, has closed a strategic investment by Chevron Technology Ventures (CTV) to support the development of stationary energy storage systems for demand charge management at electric vehicle (EV) charging stations.
Researchers from Tatung and National Cheng Kung Universities in China, and Case Western Reserve University in Ohio, report manufacturing a new oxygenate additive for diesels (bio or petroleum) using glycerol (a major byproduct of biodiesel production), dimethyl sulfate (DMS), and sodium hydroxide pellets as raw materials.
Researchers at Isfahan University of Technology (Iran) report the efficient production of cellulosic ethanol from rice straw using a new sodium carbonate pretreatment method. Rice straw was treated with sodium carbonate (Na 2 CO 3 )prior to enzymatic hydrolysis and fermentation. and 1 M sodium carbonate solution. Resources.
Two chemists at Brown University have streamlined the conversion of waste vegetable oil (WVO) into biodiesel, eliminating the need for corrosive chemicals to perform the reactions. Current techniques for the conversion of waste vegetable oil to biodiesel take time, are costly and are inefficient. WVO to Biodiesel. —Jason Sello.
Hexana aims to implement a fast neutron and sodium-cooled reactor, integrating a high-temperature storage device. An adjoining conversion system will allow it to produce electricity as needed and flexibly to compete with gas-fired power plants but also to supply heat directly to nearby energy-intensive industries.
Researchers in Sweden and Spain have devised a three-step process for the conversion of precipitated kraft lignin from black liquor into green diesel. Their paper appears in the journal ChemSusChem. The kraft process converts wood into wood pulp for paper production. tons of black liquor dry solids.
Sienicki (2009) Investigation of alternative layouts for the supercritical carbon dioxide Brayton cycle for a sodium-cooled fast reactor. The S-CO 2 system is also very compact, meaning that capital costs would be relatively low. Wright et al. 2010) Operation and Analysis of a Supercritical CO 2 Brayton Cycle. SAND2010-0171 ). 2009.03.017.
Most importantly, after full conversion of the formate, the bicarbonate solution may be recharged with hydrogen to close the cycle. Bicarbonates are a component of many natural stones and are also commonly used as baking powder or sherbet (sodium bicarbonate, NaHCO 3 ). formed in the dehydrogenation.
Researchers in the Netherlands have demonstrated the direct conversion of synthesis gas through a Fischer-Tropsch process to C 2 through C 4 light olefins with selectivity up to 60 wt.% using catalysts that constitute iron nanoparticles (promoted by sulfur plus sodium) homogeneously dispersed on weakly interactive ?-alumina
Current interest areas in sustainable energy technologies are as follows: Biomass Conversion, Biofuels & Bioenergy. Advanced systems such as lithium-air, sodium-ion, as well as lithium-ion with new cathode chemistries are appropriate. Advanced Batteries for Transportation.
kWh ‘Zebra’ (Sodium nickel chloride) battery pack and a 42 kW (peak) electric motor with maximum torque of 173 N·m (128 lb-ft). The electrical conversion, recommended by the Marque, is ensured by Venturi with a guarantee of 3 years or 30,000 km. This Venturi-powered fully-electric version retains the practical features.
Researchers from George Washington University and Vanderbilt University have demonstrated the conversion of atmospheric CO 2 into carbon nanofibers (CNFs) and carbon nanotubes (CNTs) for use as high-performance anodes in both lithium-ion and sodium-ion batteries. times above that of sodium-ion batteries with graphite electrodes.
The first thing postdoctoral scholar and lead author Bingjun Xu and graduate student Yashodhan Bhawe did was to perform a thermodynamic analysis demonstrating that it is unlikely, if not impossible, to split water with a two-step cycle where there is complete conversion between the oxidized and reduced forms at below 1,000 °C.
It is usually associated with other lithium minerals; spodumene has a chemical composition of LiAlSi 2 O 6 but small amounts of sodium sometimes substitute for lithium. Once concluded, the revised terms will see MinRes responsible for operating Wodgina and Albemarle responsible for operating downstream conversion assets. Mt Marion.
These methods consume a significant percentage of the energy content in their compression and conversion and both raise safety concerns. Current prototype applications use very high pressure compressed hydrogen or cryogenically cooled liquid hydrogen.
Exceptionally high selectivity for lithium over other ions present in the brine (including sodium, potassium, magnesium, calcium, and boron), meeting specifications for subsequent direct production of battery-grade lithium hydroxide monohydrate, without the need to first produce lithium carbonate. No pre-extraction steps are required.
Many recent research and development efforts for cellulosic biofuels have explored a two-step bioconversion process involving: 1) liberation of fermentable sugars from lignocellulose; and 2) conversion of sugars into fuels and/or chemicals by fermentation. The use of ionic liquids (molten salts with melting points.
published in the ACS journal Chemical Reviews , reviews in detail four stationary storage systems considered the most promising candidates for electrochemical energy storage: vanadium redox flow; sodium-beta alumina membrane; lithium-ion; and lead-carbon batteries. Sodium-beta alumina membrane battery. In their study, Yang et al.
Although direct chemical reactions between water and certain metals—alkali metals including lithium, sodium and others—can produce a large amount of hydrogen in a short time, these reactions are too intense to be controlled. the high-school chemistry demonstration of the violent reaction between sodium and water.).
In industry, molecular hydrogen and reactive reagents such as sodium borohydride are used as reducing agents during the production of pharmaceuticals, agrichemicals and ammonia for fertiliser. We believe our new bio-mimetic design may have wide applications in chemical reduction. —Stephen Colbran.
In previous ORNL studies, carbon powders have proven useful in developing lithium-ion, sodium-ion and potassium-ion batteries and supercapacitors. The patent-pending, waste oil-to-biofuel conversion adds a new approach to waste tire recycling initiatives. —Hood et al. Resources. Adhikari, Y. Figueroa-Cosme, Y. Figueroa-Cosme, Y.
Current topics of interest include: Biomass Conversion, Biofuels & Bioenergy. Advanced systems such as lithium-air, sodium-ion, as well as lithium-ion electrochemical energy storage are appropriate. Work on commercially available systems such as lead-acid and nickel-metal hydride batteries will not be considered by this program.
This includes research on appropriate anodes, cathodes, and electrolytes for magnesium (Mg)-, sodium (Na)-, and lithium (Li)-based batteries and novel transition metal oxide- and nitride-based supercapacitor electrode materials. Sodium is another element that is less expensive than lithium. Novel cathodes and anodes.
Photo: China Southern Power Grid Energy Storage China’s first major sodium-ion battery energy storage station is now online, according to state-owned utility China Southern Power Grid Energy Storage. Large-scale sodium-ion batteries are gaining momentum due to their lower cost and abundance of raw materials compared to lithium-ion batteries.
The resulting blend exhibits properties similar to conventional biodiesel, while reducing waste and improving conversion. Biodiesel is produced from vegetable oils or animal fats via a transesterification reaction with a short chain alcohol and a basic catalyst such as sodium or potassium methoxide.
Power is provided by two air-cooled sodium nickel chloride battery packs, integrated under the floor of the vehicle so they don’t compromise luggage space or vehicle stability. Tags: Conversions Electric (Battery) Motors.
Researchers at Lund University (Sweden) have developed an optimized two-phase enzymatic (lipase) system for the conversion of plant oils to biodiesel. Applied to the solvent-free ethanolysis of rapeseed oil, the system delivered a yield of 96% under mild conditions. Under the mild conditions used, chemical catalysts were inefficient.
Such a conversion has never been done, but the report is another sign that the idea is gaining momentum—if with the slow steps of a baby needing decades to learn to walk. “A Conversion backers say the process has benefits for everybody involved. On 13 September, the U.S. However, there is one project that has made some headway.
Chemical energy storage mainly includes lead-acid batteries, nickel batteries, lithium batteries, liquid flow batteries, and sodium-sulfur batteries, and electromagnetic energy storage mainly includes supercapacitor energy storage and superconducting energy storage. What is a battery?
The ECO-Jet process also removes other harmful substances from the exhaust of engines using bunker fuel, for instance poisonous hydrocarbons and metals including vanadium, iron, nickel, silicon and sodium. The solution can be combined with a scrubber process to remove sulfur from flue gases. Bunker fuel may contain as much as 3.5
Using the alkaline sodium hydroxide as a base, after 60 hours, the acetone-butanol-ethanol production was also relatively low. Blaschek (2009) Pretreatment and Conversion of Distiller’s Dried Grains with Solubles for Acetone-Butanol-Ethanol (ABE) Production. Using the strong sulfuric acid method, there was no fuel produced.
EPA cited the Skyonics Skymine project as an example of captured CO 2 being used in the production of carbonate products—in this case, sodium carbonate and sodium bicarbonate.
The new solar cell can be excited by incident light on sunny days and raindrops on rainy days, yielding an optimal solar-to-electric conversion efficiency of 6.53% under AM 1.5 The positively charged ions, including sodium, calcium, and ammonium ions, can bind to the graphene surface.
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