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Sample UDRI solid-state, rechargeable lithium-air batteries, and Dr. Binod Kumar. Engineers at the University of Dayton Research Institute (UDRI) have developed a solid-state, rechargeable lithium-air battery. It was subjected to 40 charge–discharge cycles at current densities ranging from 0.05 Electrochem.
Diagram of the STAIR (St Andrews Air) cell. Oxygen drawn from the air reacts within the porous carbon to release the electrical charge in this lithium-air battery. Lithium-air batteries use a catalytic air cathode in combination with an electrolyte and a lithium anode. Click to enlarge.
charge cycle, K?O Researchers at Ohio State University (OSU) have demonstrated the concept of a potassium-air (K?O In a paper published in the Journal of the American Chemical Society , they reported a charge/discharge potential gap smaller than 50 mV at a current density of 0.16 The charge overpotential ?
Argonne National Laboratory, which has contributed heavily to the research and development of Li-ion battery technology, is now pursuing research into Lithium-air batteries. Li-air batteries use a catalytic air cathode that converts oxygen to lithium peroxide; an electrolyte; and a lithium anode.
A team from Hanyang University (Korea) and University of Rome Sapienza (Italy) have demonstrated a lithium–air battery capable of operating over many cycles with capacity and rate values as high as 5,000 mAh g carbon ?1 1 and 3 A g carbon ?1 1 , respectively. Nature Chemistry doi: 10.1038/nchem.1376 1376 10.1038/nchem.1376.
Researchers at MIT, the University of Pittsburgh, and Sandia National Laboratories have used transmission electron microscope (TEM) imaging to observe the electrochemical oxidation of Li 2 O 2 , providing insights into the rate-limiting processes that govern charge in Li–O 2 cells. —Zhong et. —Yang Shao-Horn.
The awards are being made to companies and universities across New York that are involved in advanced research and development of energy storage applications that could benefit transportation, utility Smart Grid applications, renewable energy technologies, and other industries. Next-generation lithium-ion rechargeable batteries.
Generalized form of the molten air battery. Researchers at George Washington University led by Dr. Stuart Licht have introduced the principles of a new class rechargeable molten air batteries that offer amongst the highest intrinsic electric energy storage capabilities. Licht et al. Click to enlarge. Earlier post.] Licht et al.
Researchers at the University of St. Andrews in Scotland report in a paper in the journal Nature Materials that titanium carbide (TiC) may represent a viable, stable cathode for rechargeable lithium-air batteries. Li-air batteries are receiving intense interest because of their extremely high theoretical specific energy.
Carbon is seen as an attractive potential cathode material for aprotic (non-aqueous) Lithium-air batteries, which are themselves of great interest for applications such as in electric vehicles because of the cells’ high theoretical specific energy. A team at the University of St. Oxidation of Li 2 CO 3 on charging to ?4
Clemson University will develop a lightweight, multi-material passenger vehicle body structure, addressing challenges in joining dissimilar materials. Novel Organosulfur-Based Electrolytes for Safe Operation of High Voltage Lithium-ion Batteries Over a Wide Operating Temperature. SUNY University @ Stony Brook. General Motors.
Very high energy density rechargeable lithiumair (or Li-O 2 ) batteries are of great interest for future electrified transportation because at best their practical energy density could approach that of current gasoline engined vehicles (after factoring in tank-to-wheel efficiencies). Earlier post.).
Lithium-air batteries, with a theoretical gravimetric energy density of ?3500 Lithium-ion rechargeable batteries are based on a pair of intercalation electrodes. On charging, lithium ions move from the cathode through the electrolyte and insert into the anode; discharging reverses the process. Earlier post.).
The Graz University of Technology (TU Graz) in Austria has launched the Christian Doppler (CD) Laboratory for Solid-State Batteries. The goal is to achieve immensely higher energy and power densities than conventional lithium-ion batteries with liquid electrolyte, with the additional benefit of being fireproof.
Vorbeck, a manufacturer and developer of applications using its proprietary graphene material ( earlier post ), optioned the technology for use in a graphene-based electrode for lithium-air and lithium-sulfur batteries.
Discharge–charge performance of lithium-oxygen batteries with (a) GNSs, (b) BP-2000, and (c) Vulcan XC-72 cathodes at a current density of 75 mA g -1. mAh g -1 —the highest capacity of any carbon-based materials in lithium-oxygen batteries reported so far, according to the team. Click to enlarge.
Lithium-air batteries are looked to by many as a very high-energy density next-generation energy storage solution for electric vehicles. One reaction that hasn’t been fully explained is how oxygen blows bubbles inside a lithium-air battery when it discharges. The paper is published in the journal Nature Nanotechnology.
BioSolar’s cathode technology, which has been the primary focus of its university-led research and development efforts, is a novel conductive polymer material that leverages fast redox-reaction properties rather than conventional lithium-ion intercalation chemistry to enable rapid charge and discharge.
NC State University. Medical University of South Carolina. Columbia University. Li-Air Battery : Development Of Ultra-high Specific Energy Rechargeable Lithium/Air Batteries Based On Protected Lithium Metal Electrodes. A123 Systems, Rutgers University). of Georgia). Clemson Univ.,
research facilities for scientists from universities, industry, and other laboratories, as well as to ORNL researchers: Building Technologies Research and Integration Center (BTRIC). solvent system and the resulting charge transfer kinetics at various current densities is critical. ORNL operates nine user facilities—i.e.,
A multinational team including researchers from the BMW Group have optimized an ionic liquid electrolyte for Li-air batteries, which resulted in a stable electrode-electrolyte interface and a highly reversible charge-discharge cycling behavior in a test Li-air coin cell. Earlier post.). discharge cycling process.
Schematic illustration of the aqueous rechargeable lithium battery (ARLB) using the coated lithium metal as anode, LiMn 2 O 4 as cathode and 0.5 Researchers from Fudan University in China and Technische Universität Chemnitz in Germany have developed an aqueous rechargeable lithium battery (ARLB) using coated Li metal as the anode.
An international team from MIT, Argonne National Laboratory and Peking University has demonstrated a lab-scale proof-of-concept of a new type of cathode for Li-air batteries that could overcome the current drawbacks to the technology, including a high potential gap (>1.2 V) V in O 2 (gas) → O x− (condensed phase), and η charging > 1.1
Last year, researchers at George Washington University led by Dr. Stuart Licht introduced the principles of a new class rechargeable molten air batteries that offer amongst the highest intrinsic electric energy storage capabilities. The iron molten air battery; illustration of the charge/discharge in molten carbonate.
ARPA-E said that the technology uses a novel architecture that has potential for very high energy density because it decouples the two functions of capacitors: charge separation and breakdown strength. US Patent Applications Nº 20150044581: Solid State Lithium-Air Based Battery Cell. Earlier post.). Earlier post.). Batteries'
Chemists from the University of Waterloo have successfully resolved two of the most challenging issues surrounding lithium-oxygen batteries, and in the process created a working battery with near 100% coulombic efficiency. Thermodynamics and configuration of the Li-O 2 cell. (A)
(a) Charge and discharge voltage curves in repeated charge/discharge cycles at 45 mA g ?1. b) Charge and discharge voltage curves at various current densities (13.5–1080 Researchers at the University of Tokyo, led by Dr. Noritaka Mizuno (“oxygen rocking”, earlier post ), in collaboration with Nippon Shokubai Co.,
Lithium-air (Li-O 2 ) batteries are among the nost energy-dense electrochemical platforms for mobile energy storage, and are thus considered promising for electrified transportation. the formation of a stable interphase with lithium, protecting the metal while promoting ion transport.
However, to enable greater affordability and PEV accessibility for all Americans, VTO seeks new battery chemistries and cell technologies to reduce the cost of electric vehicle battery packs by more than half, to below $80/kWh, while increasing driving range to 300 miles and decreasing charge time to 15 minutes or less by 2028.
Researchers at the University of Cambridge have developed a working laboratory demonstrator of a lithium-oxygen battery which has very high energy density, is more than 90% efficient, and, to date, can be recharged more than 2000 times, showing how several of the problems holding back the development of these devices could be solved.
Also on the list of five is the arrival of advanced batteries, including air batteries (e.g., Lithiumair), but targeted initially at small devices. Kyoto University and IBM Research - Tokyo have developed a system that can simulate a broad range of urban transport situations involving millions of vehicles.
A team at the University of Michigan (U-M) has used operando video microscopy to develop a comprehensive understanding of the voltage variations observed during Li metal cycling, which is directly correlated to dendrite growth. However, the Li-metal electrodes in these next-generation batteries are especially prone to forming dendrites.
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