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Li metal anodes and Ni-rich layered oxide cathodes with high reversible capacities are promising candidates for the fabrication of high energy density batteries. Li/Li + ). O 2 full cell, with a high Coulombic efficiency of 99.98% after 100 cycles at 25 °C. —Lee et al. Yongwon Lee et al. 2019.104309.
Researchers at Pacific Northwest National Laboratory (PNNL) have used a novel Ni-based metal organic framework (Ni-MOF) significantly to improve the performance of Li-sulfur batteries by immobilizing polysulfides within the cathode structure through physical and chemical interactions at molecular level. Li-S anode work.
Researchers from Hanyang University in Korea and the BMW Group have developed a new fully operational, practical Li-ion rechargeable battery combining high energy density with excellent cycle life. g cm -3 ; a two-sloped full concentration gradient (TSFCG) Li[Ni 0.85 O 2 , Li[Ni 0.85 O 2 (NCM) and Li[Ni 0.8
C 16 ) range straight-chain alkanes and/or branched-chain alkanes, the team notes in their paper in the ACS journal Energy & Fuels. To our knowledge, there is no report about the production of diesel or jet fuel range cycloalkane by the combination of HAA [hydroxyalkylation/alkylation] and HDO [hydrodeoxygenation] reactions.
Korea) are developing a new advanced lithium-ion battery featuring a high capacity Sn-C nanostructured anode and a high rate, high-voltage Li[Ni 0.45 In a previous paper we described a novel design battery formed by combining a high capacity nanostructured tin-carbon (Sn-C) anode with a high voltage LiNi 0.5 O 4 spinel cathode.
The working concept of I3 – /I – redox reaction in the aqueous Li-I 2 battery. A team from Japan’s RIKEN, led by Hye Ryung Byon, has developed a lithium-iodine (Li-I 2 ) battery system with a significantly higher energy density than conventional lithium-ion batteries. Schematic illustration of the aqueous Li-I 2 battery.
The objective of the projects is to develop cells that provide more than 200 Wh/kg energy density, along with long cycle life and excellent abuse tolerance to enable 40-mile-range plug-in hybrid (PHEV) and electric vehicles (EVs). One common attribute of all the projects is the use of some form of silicon-based material for the anode.
As an example, the military’s BB-2590 Li-ion battery used in a range of portable systems calls for a cycle life of ≥224 and ≥ 3 years.). LIB capacity is limited in part by the intercalation of Li ions by the anode material—i.e., Envia’s highest capacity silicon-carbon anode. Click to enlarge.
A team from Zentrum für Sonnenenergie- und Wasserstoff-Forschung (ZSW) in Germany reports in a paper in the Journal of Power Sources that the interaction of high-rate and low-temperature cycling increases the safety hazard for Li-ion batteries. In that that study, they cycled the cells at temperatures ranging from -20 °C to +70 ?C
As reported in an open-access paper in the RSC journal Energy & Environmental Science , Li||LiNi 0.8 O 2 (NCM811) cells, which can work in a wide operating temperature range from ?30 Li||NCM811 cells with a thin (50 ? For example, with increasing nickel content, Ni?rich off voltages of 4.7 off voltage (> 4.5 Resources.
Researchers at the University of Akron have developed hierarchical porous Mn 3 O 4 /C nanospheres as anode materials for Li-ion batteries. mA/g), excellent ratability (425 mAh/g at 4 A/g), and extremely long cycle life (no significant capacity fading after 3000 cycles at 4A/g) as an anode in a Li-ion battery. Li/Li + ).
This includes research on appropriate anodes, cathodes, and electrolytes for magnesium (Mg)-, sodium (Na)-, and lithium (Li)-based batteries and novel transition metal oxide- and nitride-based supercapacitor electrode materials. Magnesium is much more abundant in the Earth’s crust, making it less expensive than Li by a factor of 24.
Cycling performance of Li/SeS 2 ?C, Unlike the widely studied Li/S system, both Se and Se x S y can be cycled to high voltages (up to 4.6 However, both Li/S and Li/O 2. systems suffer from cycling performance issues that impede their commercial applications: Li/O 2. C) and metallic Li and Na. C, Na/SeS 2 ?C,
Recently, the technique has been miniaturized into a handheld device (HH LIBS) capable of analyzer any element, depending on the spectrometer range chosen for the device. SciAps recognizes that no single tool solves every problem. Don’t need REE performance? Then substitute the X-505 or X-550 instead. About the Instruments.
Researchers at the University of Maryland (UMD), the US Army Research Laboratory (ARL), and Argonne National Laboratory (ANL) have developed a non-flammable fluorinated electrolyte that supports the most aggressive and high-voltage cathodes in a Li-metal battery. Li metal offers one of the highest specific capacities (3,860 mAh g ?1
A Mn-spinel cathode/carbon anode system has calendar life issues during cycling and again at high temperatures. While other researchers have looked at stabilizing the spinel, Amine said, Argonne looked at replacing the carbon with a lithium titanate material. XRD of new Argonne nano-Li 4 Ti 5 O 12 spinel. Ni 0.175 Co 0.10
Both EnerDel and AESC, Nissan’s Li-ion JV, work with that chemistry. million USABC research project, 50% cost-shared with DOE, in partnership with ANL on developing a battery system that matches the safety of its lithium titanate anode (Li 4 Ti 5 O 12 ) with a safe, high voltage 4.8V Wide temperature stability range, -30 to +50 °C.
Tesla Motor’s Co-founder and Chief Technology Officer JB Straubel signed a 5-year research agreement with Dalhousie University’s Jeff Dahn, Li-ion battery researcher with the Faculty of Science, and his group of students, postdoctoral researchers and technical staff. combinatorial solutions handling robot for respirator carbons.
Researchers from Nanyang Technical University (NTU) in Singapore have shown high-capacity, high-rate, and durable lithium- and sodium-ion battery (LIB and NIB) performance using single-crystalline long-range-ordered bilayered VO 2 nanoarray electrodes. This is important in boosting the high-rate performance in both Li and Na ion storage.
Substantial progress in battery technology is essential if we are to succeed in an energy transition towards a more carbon-neutral society. Under such a scenario, the production of Li-ion batteries should expand hugely over the years to come, hence reviving the issue of finite Li reserves. —Grey and Tarascon.
Carbon Fiber Polymer Composite. Temperature range of ambient air, °C. -40 for high-energy batteries for use in PHEV40 (PHEVs with a 40 mile all electric range) and EV light-duty vehicles. Critical barriers exist for the implementation of lithium-ion (Li-ion) batteries in electric drive vehicle applications.
V vs Li/Li + ). A number of different nanophase forms of silicon show promise in addressing that problem, including nanocrystals; nanocomposites with either carbon or other phases inactive to lithium; nanoporous materials; nanowires; bundled Si nanotubes; and thin films. and 82 ± 2% at a rate of 0.05 Song et al.
batteries using the same process of ion insertion and removal as in Li-ion batteries—have been discussed in the literature for some time. For cathode materials, the reversible, stable capacity of bulk Na + intercalation is usually limited to levels far below what can be obtained in Li-ion electrode materials. Earlier post.)
Stuart Licht ( earlier post ) have developed a new process that transforms CO 2 into a controlled selection of nanotubes (CNTs) via molten electrolysis; they call the process C2CNT (CO2 into carbon nanotubes). Molten carbonate electrosynthesized boron-doped CNTs exhibit high electrical conductivity. —Ren et al. Licht (2017).
Carbon Fiber Polymer Composite. The objective of AOI 7 is to develop in situ microscopy and spectroscopy tools capable of identifying physical and chemical changes of Li battery components during charging and discharging with time, depth, and space resolution, and that will allow detailed monitoring of processes at relevant length scales.
We also think that with more people realizing that global warming is our greatest challenge, and that evolving the transportation sector to zero-carbon via cellulosic ethanol plug-in hybrids plus electricity from renewable sources may be our best strategy, the discussions about payback are a narrow answer to big questions.
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