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IBM Almaden Lab Exploring Lithium-Air Batteries for Next-Generation Energy Storage

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General schematic of a lithium-air battery. The team plans to explore rechargeable Lithium-Air systems, which could offer 10 times the energy capacity of lithium-ion systems. Original lithium-air batteries—aqueous batteries, or with an aqueous electrolyte/air interface—were primary cells—i.e.,

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Researchers Develop Lithium-Water Electrochemical Cell for the Controlled Generation of H2 and Electricity

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Schematic representation and operating principles of the lithiumwater electrochemical cell used for hydrogen generation: (1) external circuit and (2) inside of lithiumwater electrochemical cell. the high-school chemistry demonstration of the violent reaction between sodium and water.). Source: Wang et al.

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ARPA-E Selects 37 Projects for $106M in Funding in Second Round; Electrofuels, Better Batteries and Carbon Capture

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ARPA-E’s first solicitation awarded $151 million to 37 projects aimed at transformational innovations in energy storage, biofuels, carbon capture, renewable power, building efficiency, vehicles, and other areas. This process is less than 1% efficient at converting sunlight to stored chemical energy. Water will be the primary byproduct.

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New nanolithia cathodes may address technical drawbacks of Li-air batteries; scalable, cheap and safer Li-air battery system

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loss after 130 cycles in lithium-matched full-cell tests against Li 4 Ti 5 O 12 anode), as well as a round-trip overpotential of only 0.24 V. Further, the cathode is automatically protected from O 2 gas release and overcharging through the shuttling of self-generated radical species soluble in the carbonate electrolyte.

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IBM releases fifth annual Next Five in Five list of near-term significant innovations; personalized routing for commuting/transportation makes the cut

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Also on the list of five is the arrival of advanced batteries, including air batteries (e.g., Lithium air), but targeted initially at small devices. Batteries today have a number of problems, chiefly, the heavy metal-oxides used inside the battery greatly limit the amount of energy it can store, IBM notes.

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IBM Almaden Researchers Say Li-Air Batteries Offer Promise for Transition to Electrified Transportation, But Face Challenges and Multi-Decade Development Cycle

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Typical thermal runaway of a Li-ion battery due to overcharging or internal shorts is not a possibility in Li-air batteries because of the rate-limited surface nature of the reaction, i.e., the reactant O 2 is not stored in the battery. Wilcke (2010) Lithium-Air Battery: Promise and Challenges. Recommended key research.

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