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Researchers from the University of Illinois at Chicago (UIC) have identified molybdenum disulfide as a promising cost-effective substitute for noble metal catalysts for the electrochemical reduction of carbon dioxide. Carbon Capture and Conversion (CCC) Catalysts Fuels' Paaren Graduate Fellowship.
Researchers at Colorado State University have shown that under relatively mild conditions (?140 The results, they say, are broadly relevant to reactions involving the use of IL-H 2 O mixtures (as solvents, reactants, or catalysts), including, but not limited to, organic catalysis, electrochemistry, and biomass processing or conversion.
NEC Corporation, NEC TOKIN Corporation and TOHOKU UNIVERSITY have jointly created a thermoelectric (TE) device using the spin Seebeck effect (SSE) with conversion efficiency 10 times higher than a test module that was produced based on a multi-layered SSE technology published by the Tohoku University group in 2015.
A collaboration including researchers from Boston College, MIT, the University of Virginia and Clemson University have achieved a peak ZT (thermoelectric figure of merit) of 0.8 And a team from Northwestern University and the University of Michigan reported experimentally achieving a ZT of 1.7 The study by Yan et al.
Researchers at MIT and Stanford University have developed new battery technology for the conversion of low-temperature waste heat into electricity in cases where temperature differences are less than 100 degrees Celsius. These features lead to a high heat-to-electricity energy conversion efficiency of 5.7% Click to enlarge.
Schematic representation of the integrated conversion of hemicellulose and cellulose portions of lignocellulosic biomass to furfural and GVL, using a portion of the GVL as a solvent and the remainder for conversion to butene oligomers as hydrocarbon. 80%) from direct conversion of hemicellulose in corn stover. Alonso et al.
One way to mitigate high feedstock cost is to maximize conversion into the bioproduct of interest. This maximization, though, is limited because of the production of CO 2 during the conversion of sugar into acetyl-CoA in traditional fermentation processes. Wiedel, Jennifer Au, Maciek R. Antoniewicz, Eleftherios T.
However, some compounds like FeF 3 are capable of transferring multiple electrons through a more complex reaction mechanism, called a conversion reaction. Iron fluoride, an intercalation-conversion cathode for lithium-ion batteries, promises a high theoretical energy density of 1922?Wh?kg
A new material that can selectively capture CO 2 molecules and efficiently convert them into useful organic materials has been developed by researchers at Kyoto University, along with colleagues at the University of Tokyo and Jiangsu Normal University in China. —Susumu Kitagawa, materials chemist at Kyoto University.
Researchers at the University of Cincinnati, Ohio, report on the development of a catalytic hydroboration system for the “highly efficient” reduction of CO 2 with a borane and subsequent hydrolysis of the resulting methoxyboryl species to produce methanol (CH 3 OH) in good yield. Article ASAP doi: 10.1021/ja103982t.
A new spatially-explicit life cycle assessment of five different “sun-to-wheels” conversion pathways—ethanol from corn or switchgrass for internal combustion vehicles (ICVs); electricity from corn or switchgrass for battery-electric vehicles (BEVs); and photovoltaic electricity for BEVs—found a strong case for PV BEVs.
AI agents will make calls on our behalf, conversing with others in natural language. A ring modulator has several advantages: It is computationally simple, can be applied in real-time, does not affect the intelligibility of the voice, and--most importantly--is universally robotic sounding because of its historical usage for depicting robots.
Magnetite, among other conversion-type electrode materials (i.e., In the following charge, this conversion reaction is not completely reversible—residues of metallic iron and lithium oxide remain. Because the conversion reaction is not fully reversible, these residual products accumulate.
A team from The University of Manchester and East China University has developed a process for the direct hydrodeoxygenation of raw woods into liquid alkanes with mass yields up to 28.1 wt% Nature Communications 7, Article number: 11162 doi: 10.1038/ncomms11162. wt% over a multifunctional Pt/NbOPO 4 catalyst in cyclohexane.
Now, researchers at Washington State University, University of New Mexico, Eindhoven University of Technology, and Pacific Northwest National Laboratory report developing a catalyst that can both withstand high temperatures and convert pollutants at near room temperature. Hensen, Yong Wang & Abhaya K.
The team also suggested that algae systems can be either net energy positive or negative depending on the specific combination of cultivation and conversion processes used. Unit operations pertinent to assessment of four specific conversion pathways are shaded (gray) in panels A-D at bottom. Credit: ACS, Clarens et al. Earlier post.)
Now, an international research team has discovered and characterized a new family of cytochrome P450 enzymes critical to improving the conversion of lignin. Demethylation is the simple chemistry of removing a methyl group, and the microbial conversion of lignin relies on this critical reaction. —Gregg Beckham. Houk, Gregg T.
Researchers at the University of Exeter (UK) have developed a novel p-type LaFeO 3 photoelectrode using an inexpensive and scalable spray pyrolysis method. Cost effective solar fuel generation is hindered by the semiconductor material not meeting certain essential criteria to achieve highly efficient solar to hydrogen conversion.
Researchers at the Norwegian University of Science and Technology (NTNU) have developed a calculation procedure to estimate the maximum theoretical yields, as well as predictions of the conversion efficiencies in terms of mass, carbon, and energy efficiency, of selected biorefinery production chains. Click to enlarge.
Sulfides are common materials, but the MIT scientists are experimenting with them under extreme conditions such temperatures from 800 to 3,000 degrees Fahrenheit that are used in manufacturing plants but not in a typical university lab. Cite this article Stinn, C., Allanore, A. 2021) “Selective sulfidation of metal compounds.”
Korea), Georgia Institute of Technology, and Dong-Eui University (S. The power density of a commercialized low-temperature SOFC system developed by researchers at the University of Maryland and Redox Power is also more than 2W cm -2 , earlier post.). Scientific Reports 3, Article number: 2426 doi: 10.1038/srep02426.
Researchers at the University of Waterloo (Canada) have demonstrated a single-step solid acid-catalyzed process with the potential for industrial-scale production of biodiesel from high free fatty acid (FFA) feedstocks. Energy Fuels , Article ASAP doi: 10.1021/ef901258b. Aijaz Baig and Flora T.
A team of scientists at the University of Cambridge has reported the light-driven photoreforming of cellulose, hemicellulose and lignin to H 2 using semiconducting cadmium sulfide quantum dots in alkaline aqueous solution. A paper on their work is published in the journal Nature Energy. Wakerley, Moritz F. Kuehnel, Katherine L. Ly, Timothy E.
An alternative method is its primary conversion into bio-oil by fast pyrolysis. Energy Fuels , Article ASAP doi: 10.1021/ef1010995. However, the biomass is difficult to collect and store, and the energetic density of it is low, which leads to high transportation and store costs.
A study by a team from the State Key Laboratory of Heavy Oil Processing, China University of Petroleum found that fluid thermal processing of. Direct thermal conversion can be a more feasible process to obtain bitumen-derived liquid products from oil-wet oil sand, they say. Energy & Fuels Article ASAP doi: /10.1021/ef200644.
Researchers at Colorado State University have found that a microalgae biodiesel process using currently available technologies can show improvement in lifecycle GHG emissions and net energy ratio (NER) compared to soybean-based biodiesel. Article ASAP doi: 10.1021/es102052. Credit: ACS, Click to enlarge.
Now, researchers from the University of Illinois at Urbana-Champaign and UC Berkeley have engineered yeast to convert cellulosic sugars and toxic levels of acetate together into ethanol under anaerobic conditions. Acetic acid is toxic to fermenting microorganisms and negatively influences sugar fermentation and biofuel yields. cerevisiae.
Researchers in South Korea have developed a simple, low-cost and eco-friendly method of creating nitrogen-doped graphene nanoplatelets (NGnPs) with excellent catalytic performance in both dye-sensitized solar cells and fuel cells to replace conventional platinum (Pt)-based catalysts for energy conversion. —Jeon et al. —Jeon et al.
Researchers at the University of Delaware have developed a highly selective nanoporous silver catalyst capable of electrochemically reducing carbon dioxide to carbon monoxide with 92% efficiency. The carbon monoxide then can be used to produce synthetic fuels and chemicals. The researcher reported their findings in Nature Communications.
Researchers at Carnegie Mellon University have developed a new catalyst—iron-centered tetraamido macrocyclic ligand (Fe-TAML)—that efficiently catalyzes water oxidation. Article ASAP doi: 10.1021/ja104766. Studies are underway to improve the usefulness of Fe-TAMLs for water splitting. Ellis et al. Resources. Chadwick Ellis, Neal D.
A team at Stanford University is proposing using solid oxide fuel cells as the basis for a method for electricity production from oil shale with in situ carbon capture (EPICC) as a means to provide transportation services from oil shale with greatly reduced CO 2 emissions. Conversion to work via. Scale of conversion to work.
A new review article in the journal Science highlights emerging opportunities to increase the transformation of lignin to value-added products—i.e., lignin valorization. Ragauskas et al. courtesy of Oak Ridge National Laboratory.] Click to enlarge. —Ragauskas et al. Ragauskas, et al.,
To our knowledge, this level of conversion of carbohydrate feedstocks into simple organic molecules is unrivaled in the literature. Because working at higher temperatures afforded no real advantages in terms of carbohydrate to CMF conversion, reactions were generally run below 100 °C to avoid this hydrolysis reaction.
A team from the University of Oxford (UK) and CNRS (France) has developed an optimized system for the photocatalytic production of hydrogen using an hydrogenase and photosensitizer co-attached to a TiO 2 nanoparticle. Article ASAP doi: 10.1021/ja907923r. Source: Reisner et al./ Click to enlarge. —Reisner et al.
Rau; CO 2 Mitigation via Capture and Chemical Conversion in Seawater. Article ASAP doi: 10.1021/es102671x. t, and societal acceptability of this and other approaches to CO 2 emissions reduction and ocean acidity mitigation. —Greg Rau.
A team from the University of Exeter (UK), with support from Shell Technology Centre Thorton, has modified strains of E. Hydrocarbons produced by cells expressing the synthetic alkane pathway (CEDDEC) or the cyanobacterial alkane pathway (AR and AD from N. punctiforme) without modifications to the fatty acid pool. Howard et al.
A team at China’s Southeast University in Nanjing is developing a process to improve the thermal stability and heating value of bio-oil produced using catalytic fast pyrolysis. Energy Fuels , Article ASAP doi: 10.1021/ef900720m. A paper on their work was published online in the ACS journal Energy & Fuels on 19 October.
Researchers at Tsinghua University in China have shown that sugarcane juice is a good feedstock for biodiesel production, when used to support the growth of the alga Chlorella protothecoides by heterotrophic fermentation. Conversion ratios of sugar/biomass and sugar/oil using SCH were 15.2 Energy Fuels , Article ASAP.
Researchers at the University of Alberta are developing , and, via their spin-out AdvEn Solutions working to commercialize, a new high power- and -energy density battery system: lithium-carbon-fluorine (Li-C-F). (b) Ragone plot, comparing Li-CNT-F batteries with other batteries in terms of weight of cathode materials. Click to enlarge.
Researchers at the University of New Mexico found in a study of the catalytic conversion of Camelina Sativa oil to biodiesel through both conventional heating and microwave radiation that the microwave-heating method consumed less than 10% of the energy to achieve the same yield as the conventional heating method. Prafulla D.
Researchers at Nanjing University and Anhui Polytechnic University in China have synthesized zinc orthogermanate (Zn 2 GeO 4 ) ultralong nanoribbons which show promising photocatalytic activity toward the reduction of CO 2 into renewable methane (CH 4 ) and water. Article ASAP doi: 10.1021/ja1068596. Credit: ACS, Liu et al.
Increased availability of low CO 2 sources of electricity and hydrogen could counter-intuitively delay, rather than accelerate, a large-scale transition to an electric and/or hydrogen vehicle fleet, according to a new study by researchers from Ford Motor Company and Chalmers University of Technology in Sweden. Wallington et al. Anderson, S.
Model scope includes all upstream processing of biomass material; conversion to liquid or solid fuel is intentionally excluded. Biofuel conversion processes were excluded from the scope of the analysis. These so-called ‘indirect’ changes are associated with conversion of arable land into production and were not included here.
The research, published in the journal Joule , builds on innovations first reported in Science in 2017 by the same research group at the University of California San Diego and the university spinout South 8 Technologies. In contrast, most of conventional electrolytes fail to work below minus 20 ?C. 1721646).
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